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Showing 1 to 1 of 1 for “"stereoretentive transmetalation"”.
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Ligand design principles for perfecting stereoretention in Suzuki-Miyaura cross-coupling of unactivated CSP3 boronic acids
… critical to understand the competition between stereoretentive and stereoinvertive transmetalation mechanisms. Achieving perfect transfer of stereochemistry from building blocks to products required that one of these transmetalation pathways be completely mitigated. By systematically studying …