Global ETD Search
Search theses and dissertations gathered from participating repositories worldwide. Every result links back to the library that holds it. No account is needed.
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Showing 1 to 2 of 2 for “"solvent isotope effect"”.
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Understanding the mechanism of androgen biosynthesis
… this essential question. Presence of an inverse solvent isotope effect during dehydroepiandrosterone formation, as well as functional lyase catalysis by a CYP17A1 mutant possessing an impaired proton-delivery network, strongly support the hypothesis that a ferric peroxoanion is responsible for …
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Investigating the rate-limiting step of mitochondrial complex I catalysis
… Using the proteoliposomes system, the pH and solvent isotope dependence of kinetic parameters of purified bovine and *Yarrowia lipolytica* complex I mutants were measured under a range of conditions. I find complex I robustly displays a solvent kinetic isotope effect (KIE), signifying that the …