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Showing 1 to 3 of 3 for “"soft enolization"”.
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1. C-C Bond Formation via Soft Enolization and Umpolung-like Chemistry 2. Electrophilic Fluorination of Organozinc Reagents
… synthetic strategies towards C-C bond formation, soft enolization and Umpolung-like chemistry. The direct synthesis of 1,3-diketones and β-keto thioesters using in good yields and with wide substrate tolerance was possible using our soft enolization strategy using crude acyl chlorides. Another C-C …
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Diversification of 4-Alkylpyridines: Mining for Reactivity with Alkylidene Dihydropyridines
… in pharmaceutical development. Using a soft enolization approach, we can diversify alkyl pyridines under mild conditions via alkylidene dihydropyridines (ADHPs). Recent work in our group has demonstrated the utility of ADHPs in palladium-catalyzed reactions. However, the fundamental …
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Cooperative activation of biomass-derived oxygenates with Lewis acid zeolites
… pairs in the Si-O-M framework ensemble promote soft enolization through a-proton abstraction. These Lewis acidic zeolites maintain activity in the presence of water and, unlike traditional base catalysts, in acidic solutions, enabling synthesis of unsaturated dicarboxylic acid esters via aldol …