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Showing 1 to 2 of 2 for “"silylative coupling"”.
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Ruthenium-Catalyzed Transformations for the Synthesis of Conjugated Dienes
… was accomplished via a recently developed tandem silylative coupling using RuHCl(CO)(PCy3)2. The reaction optimization, mechanistic hypothesis and substrate scope for the coupling with acrylates and vinyl boronates is described. The vinyl boronate scope and alkyne scope is presented, in addition …