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Showing 1 to 1 of 1 for “"sigmatrope Umlagerungen"”.
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Viridiofungins and xeniolide F: target oriented synthesis using different rearrangement reactions of a common substrate class
The present dissertation covers the total synthesis of viridiofungin triesters and studies toward the total synthesis of xeniolide F. In both cases, sigmatropic rearrangements of α-allyloxy substituted α,β-unsaturated esters are employed: for the viridiofungin ester synthesis a [2,3]-Wittig …