Global ETD Search
Search theses and dissertations gathered from participating repositories worldwide. Every result links back to the library that holds it. No account is needed.
Results
Showing 1 to 1 of 1 for “"shift from concerted to stepwise"”.
-
Electrochemical oxidation of aliphatic carboxylates: Kinetics, thermodynamics, and evidence for a shift from a concerted to a stepwise mechanism in the presence of water
… for tetra-n-butylammonium acetate was determined to be 0.60 ± 0.10 (vs. Ag/ (0.1 M) AgNO₃) in anhydrous acetonitrile. The results also indicated the mechanism of oxidation was concerted dissociative electron transfer (cDET), rather than stepwise as was previously reported. To further investigate …