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Showing 1 to 3 of 3 for “"salicylaldiminato"”.
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Investigations into cyclopropanation and ethylene polymerization via salicylaldiminato copper (II) complexes
Two distinct overall research objectives are in this Master’s thesis. Very little relates the two chapters apart from the ligands. The first chapter addresses diastereoselective homogeneous copper catalyzed cyclopropanation reactions. Cyclopropanation of styrene and ethyl diazoacetate (EDA) is a …
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Structural studies of some copper(II) coordination compounds
… of one crystalline form of bis-(N-ethyl-salicylaldiminato) copper(II) has revealed that the copper atom in such a compound may adopt a tetrahedrally-distorted coordination geometry under less severe steric conditions than had previously been supposed. The structures of a methylamine …
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Metal complexes as models for vitamin B₆ catalysis
… complexes, Bis[N- (2-ethoxycarbonyl-l-propyl)salicylaldiminato]copper(II) and Bis[N-(3-ethoxycarbonyl-2-propyl)salicylaldiminato]copper(II). The inertness of these two complexes to H-D exchange contrasts with the ready exchange in the absence of base of the complexes derived from a-amino …