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Showing 1 to 20 of 83 for “"ruthenium(II)"”.
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The Synthesis and Characterization of Phosphonium Indenylide Complexes of Ruthenium(II)
… indenylides 1-C9H6PPh3 (I), 1-C9H6PMePh2 (II) and1-C9H6PMe2Ph (III) have been synthesized and reacted with [CpRu(MeCN)3]PF6 to form complexes of the type [CpRu(I-III)]PF6 (V-VII) which were characterized by NMR spectroscopy, ESI MS and X-ray crystallography. In an attempt to synthesize …
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Photochemistry of a Series of Weakly Coupled Dinuclear Ruthenium(II) Complexes
… synthetic method was developed for symmetric ruthenium(II) polypyridine complexes with the form L2Ru(diphen)RuL2. The scope of the reaction was investigated in regards to the ligands, bridging ligands, and starting materials. Several ligands were successful in the synthesis, including …
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Oxidative Dehydrogenation and Kinetics of Electron Transfer of Ruthenium(ii) Ethylenediamine Compounds
Made available in DSpace on 2014-12-10T23:02:07Z (GMT). No. of bitstreams: 1 7511583.pdf: 2734783 bytes, checksum: 4966cf42d34a51852467e9d93db3519b (MD5) Previous issue date: 1974
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Discovering the Potential of Photoluminescent Ruthenium(II) Complexes as Photodynamic Therapy Agents
Anthracene was attached to light activated, ruthenium-based DNA disruptors to probe their distribution in cancer cells. The objective of this research is to understand the photophysical properties (Chapter 2), photoreactivity toward DNA and proteins (Chapter 3), and localization within cancer cells …
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The reaction of aquoamine ruthenium (II) species with nitrous oxide and azide ion
ii, 181 leaves : ill. ; 25 cm.
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Microenvironments, Binding Interactions, and Photophysics of Polyelectrolyte-Bound Tris-(2,2'-Bipyridine)ruthenium(ii)
… kinetics of tris-(2,2$\sp\prime$-bipyridine)ruthenium(II) (Ru(bpy)$\sb3\sp{2+}$) upon immobilization in "organized" or inhomogeneous media. To gain a fundamental understanding of these factors and mechanisms it was necessary to characterize the interactions between the complex and the medium …
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Application of Tris(2,2'-Bipyridyl)ruthenium(ii) Electrogenerated Chemiluminescence for Detection in Liquid Chromatography
… the application of tris(2,2$\sp\prime$-bipyridyl)ruthenium(II) (Ru(bpy)$\sb3\sp{2+}\rbrack$ electrogenerated chemiluminescence (ECL) detection to liquid chromatography (LC) and microbore LC. An important class of compounds that can be detected using Ru(bpy)$\sb3\sp{2+}$ ECL is amines, which are …
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Studies of tris(2,2'-bipyridyl)ruthenium(II) electrogenerated chemiluminescence for detection in flowing streams
… and application of tris(2,2$\sp\prime$-bipyridyl)ruthenium(II) (Ru(bpy)$\sb3\sp{2+}$) electrogenerated chemiluminescence (ECL) for detection in flowing streams. Three approaches were comparatively evaluated for use of Ru(bpy)$\sb3\sp{2+}$ as a chemiluminescent reagent in flowing streams. The three …
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Diimine complexes of ruthenium(ii), rhenium(i) and iron(ii): from synthesis to DFT studies
… rhenium(I) tricarbonyl complexes containing the diimine ligands 2,2’-bipyrazine (bpz) and 5,5’-dimethyl-2,2’-bipyrazine (Me2bpz) are discussed. When compared to similar rhenium(I) tricarbonyl complexes of 2,2’-bipyridine (bpy) and 2,2’-bipyrimidine (bpm), the Me2bpz complexes are comparable to bpm …
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The Effects of Nonionic Surfactants on the Tris(2,2'-Bipyridl) Ruthenium(Ii)-Tripropylamine Electrochemiluminescence System
When oxidized in the presence of tri-n-propylamine (TPA), the molecule Ru(bpy)₃²⁺ (bpy= 2,2'-bipyridyl) undergoes reactions to produce electrochemiluminescence (ECL). In this investigation, the effects of the nonionic surfactants Nonidet P40®, Thesit®, and Triton X-100® were studied. ECL occurs in …
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Evaluation of solid-state light-emitting devices based on the tris-chelated ruthenium (II) complexes
Organic light-emitting devices have the potential to create a new range of applications. They are versatile because their physical properties (color, emission efficiency) can be fine-tuned by the manipulation of their chemical structures. In this work, the novel technology of Ru(bpy)t-based devices …
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Aqueous Organometallic Catalysis: Nitrile Hydration Catalyzed by Ruthenium(II) 1,3,5-triaza-7-phosphaadamantane (PTA) Derived Complexes
… the synthesis and characterization of ruthenium complexes containing water-soluble 1,3,5-triaza-7-phosphaadamantane (PTA) and PTA derived ligands for the application of aqueous phase nitrile hydration. A series of PTA and PTA derivatives were characterized via solid-state NMR (SSNMR) …
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