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Showing 1 to 20 of 83 for “"ruthenium(II)"”.

  1. The Synthesis and Characterization of Phosphonium Indenylide Complexes of Ruthenium(II)

    … indenylides 1-C9H6PPh3 (I), 1-C9H6PMePh2 (II) and1-C9H6PMe2Ph (III) have been synthesized and reacted with [CpRu(MeCN)3]PF6 to form complexes of the type [CpRu(I-III)]PF6 (V-VII) which were characterized by NMR spectroscopy, ESI MS and X-ray crystallography. In an attempt to synthesize …

    queens Repository record for The Synthesis and Characterization of Phosphonium Indenylide Complexes of Ruthenium(II) (opens in a new tab)

  2. Photochemistry of a Series of Weakly Coupled Dinuclear Ruthenium(II) Complexes

    … synthetic method was developed for symmetric ruthenium(II) polypyridine complexes with the form L2Ru(diphen)RuL2. The scope of the reaction was investigated in regards to the ligands, bridging ligands, and starting materials. Several ligands were successful in the synthesis, including …

    arkansas Repository record for Photochemistry of a Series of Weakly Coupled Dinuclear Ruthenium(II) Complexes (opens in a new tab)

  3. Oxidative Dehydrogenation and Kinetics of Electron Transfer of Ruthenium(ii) Ethylenediamine Compounds

    Made available in DSpace on 2014-12-10T23:02:07Z (GMT). No. of bitstreams: 1 7511583.pdf: 2734783 bytes, checksum: 4966cf42d34a51852467e9d93db3519b (MD5) Previous issue date: 1974

    uiuc Repository record for Oxidative Dehydrogenation and Kinetics of Electron Transfer of Ruthenium(ii) Ethylenediamine Compounds (opens in a new tab)

  4. Discovering the Potential of Photoluminescent Ruthenium(II) Complexes as Photodynamic Therapy Agents

    Anthracene was attached to light activated, ruthenium-based DNA disruptors to probe their distribution in cancer cells. The objective of this research is to understand the photophysical properties (Chapter 2), photoreactivity toward DNA and proteins (Chapter 3), and localization within cancer cells …

    vt Repository record for Discovering the Potential of Photoluminescent Ruthenium(II) Complexes as Photodynamic Therapy Agents (opens in a new tab)

  5. Microenvironments, Binding Interactions, and Photophysics of Polyelectrolyte-Bound Tris-(2,2'-Bipyridine)ruthenium(ii)

    … kinetics of tris-(2,2$\sp\prime$-bipyridine)ruthenium(II) (Ru(bpy)$\sb3\sp{2+}$) upon immobilization in "organized" or inhomogeneous media. To gain a fundamental understanding of these factors and mechanisms it was necessary to characterize the interactions between the complex and the medium …

    uiuc Repository record for Microenvironments, Binding Interactions, and Photophysics of Polyelectrolyte-Bound Tris-(2,2'-Bipyridine)ruthenium(ii) (opens in a new tab)

  6. Application of Tris(2,2'-Bipyridyl)ruthenium(ii) Electrogenerated Chemiluminescence for Detection in Liquid Chromatography

    … the application of tris(2,2$\sp\prime$-bipyridyl)ruthenium(II) (Ru(bpy)$\sb3\sp{2+}\rbrack$ electrogenerated chemiluminescence (ECL) detection to liquid chromatography (LC) and microbore LC. An important class of compounds that can be detected using Ru(bpy)$\sb3\sp{2+}$ ECL is amines, which are …

    uiuc Repository record for Application of Tris(2,2'-Bipyridyl)ruthenium(ii) Electrogenerated Chemiluminescence for Detection in Liquid Chromatography (opens in a new tab)

  7. Studies of tris(2,2'-bipyridyl)ruthenium(II) electrogenerated chemiluminescence for detection in flowing streams

    … and application of tris(2,2$\sp\prime$-bipyridyl)ruthenium(II) (Ru(bpy)$\sb3\sp{2+}$) electrogenerated chemiluminescence (ECL) for detection in flowing streams. Three approaches were comparatively evaluated for use of Ru(bpy)$\sb3\sp{2+}$ as a chemiluminescent reagent in flowing streams. The three …

    uiuc Repository record for Studies of tris(2,2'-bipyridyl)ruthenium(II) electrogenerated chemiluminescence for detection in flowing streams (opens in a new tab)

  8. Diimine complexes of ruthenium(ii), rhenium(i) and iron(ii): from synthesis to DFT studies

    … rhenium(I) tricarbonyl complexes containing the diimine ligands 2,2’-bipyrazine (bpz) and 5,5’-dimethyl-2,2’-bipyrazine (Me2bpz) are discussed. When compared to similar rhenium(I) tricarbonyl complexes of 2,2’-bipyridine (bpy) and 2,2’-bipyrimidine (bpm), the Me2bpz complexes are comparable to bpm …

    wichita-thes Repository record for Diimine complexes of ruthenium(ii), rhenium(i) and iron(ii): from synthesis to DFT studies (opens in a new tab)

  9. The Effects of Nonionic Surfactants on the Tris(2,2'-Bipyridl) Ruthenium(Ii)-Tripropylamine Electrochemiluminescence System

    When oxidized in the presence of tri-n-propylamine (TPA), the molecule Ru(bpy)₃²⁺ (bpy= 2,2'-bipyridyl) undergoes reactions to produce electrochemiluminescence (ECL). In this investigation, the effects of the nonionic surfactants Nonidet P40®, Thesit®, and Triton X-100® were studied. ECL occurs in …

    mo-state Repository record for The Effects of Nonionic Surfactants on the Tris(2,2'-Bipyridl) Ruthenium(Ii)-Tripropylamine Electrochemiluminescence System (opens in a new tab)

  10. Evaluation of solid-state light-emitting devices based on the tris-chelated ruthenium (II) complexes

    Organic light-emitting devices have the potential to create a new range of applications. They are versatile because their physical properties (color, emission efficiency) can be fine-tuned by the manipulation of their chemical structures. In this work, the novel technology of Ru(bpy)t-based devices …

    mit Repository record for Evaluation of solid-state light-emitting devices based on the tris-chelated ruthenium (II) complexes (opens in a new tab)

  11. Aqueous Organometallic Catalysis: Nitrile Hydration Catalyzed by Ruthenium(II) 1,3,5-triaza-7-phosphaadamantane (PTA) Derived Complexes

    … the synthesis and characterization of ruthenium complexes containing water-soluble 1,3,5-triaza-7-phosphaadamantane (PTA) and PTA derived ligands for the application of aqueous phase nitrile hydration. A series of PTA and PTA derivatives were characterized via solid-state NMR (SSNMR) …

    unr Repository record for Aqueous Organometallic Catalysis: Nitrile Hydration Catalyzed by Ruthenium(II) 1,3,5-triaza-7-phosphaadamantane (PTA) Derived Complexes (opens in a new tab)

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