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Showing 1 to 2 of 2 for “"ring slip"”.
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Synthesis, antimicrobial activity, and catalytic activity of rhodium and iridium piano stool complexes: Teaching an old dog new tricks
… cycles were proposed, one of which invokes a ring slip transition state. Though it is unclear if the "indenyl effect" is responsible for this differing activity, it is certainly apparent that using an indenyl ligand has a notable effect in this catalytic reaction. Cyclometalation was also …
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Metal-catalyzed reactions.
… catalysts. We were interested in exploring ring slippage of the Cpx ligand to access the coordinative unsaturation necessary to accomplish a directed reaction. Generally, a 12 e- transition metal fragment is required for a directed process to occur. In the hydroboration reaction, the …