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Showing 1 to 1 of 1 for “"rhodium-alkoxo bonds"”.
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The effects of ancillary ligand properties on the reactions of rhodium diphosphine alkoxo alkene complexes
Rhodium diphosphine alkoxo alkene complexes were synthesized by the addition of unsaturated alcohols to rhodium diphosphine silylamido complexes at -78 °C. The alkoxo alkene complexes were characterized by NMR spectroscopy at 50 °C and allowed to react at either 35 °C or 70 °C. The reactions …