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Showing 1 to 20 of 64 for “"reversible addition"”.
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Investigation Of Parameters Enabling Admicellar Reversible Addition-Fragmentation Chain Transfer (Raft) Polymerization
… to implement oxygen sensitive technique such as reversible addition-fragmentation chain transfer (RAFT) polymerization in admicellar polymerization in order to obtain more advanced thin films. Our initial investigation focuses on admicellar RAFT polymerization of styrene, 4-methylstyrene, and …
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Hierarchical self-assembly of nanoparticles using reversible addition-fragmentation chain-transfer block copolymers
The hierarchical self-assembly of cadmium based quantum dots through the use of RAFT block copolymers have been investigated. The formation of cadmium selenide quantum dots within the core of tetrablock RAFT copolymers in three different solvents, dioxane, THF and DMF was investigated …
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Synthesis and Characterization of Graphene-Polymer Nanocomposites via Reversible Addition-Fragmentation Chain-Transfer Polymerization
… chains from the surface of graphene sheets via reversible addition-fragmentation chain-transfer (RAFT) polymerization. Graphene oxide was synthesized by reacting graphite with potassium permanganate and concentrated sulfuric acid. The oxidation and exfoliation of graphite was investigated using …
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Novel Precursors for Polymer-Protein-Conjugate Synthesis via Reversible Addition-Fragmentation Chain Transfer Polymerization
The RAFT polymerization of N-isopropylacrylamide with two different chain transfer agents, namely benzyl 1-pyrrolecarbodithioate and cumyl 1-pyrrolecarbodithioate, yielded polymers with narrow molecular weight distributions as well as Mn values that were in good agreement with the calculated ones. …
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Overcoming Challenges in Reversible Addition–Fragmentation Chain Transfer Polymerization using Photoinduced Electron/Energy Transfer Catalysis
… an emphasis on addressing two limitations in reversible addition–fragmentation chain transfer (RAFT) polymerization. Both methods employ photoinduced electron/energy transfer (PET) catalysis to generate radicals within the polymerization system. PET catalysis was selected as the initiation …
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The synthesis of well-defined functional homo- and block copolymers in aqueous media via Reversible Addition-Fragmentation Chain Transfer (RAFT) Polymerization
… for free radical polymerization via Reversible Addition-Fragmentation chain Transfer (RAFT) were synthesized. The new compounds bear permanently hydrophilic sulfonate moieties which provide solubility in water independent of the pH. One of them bears a fluorophore, enabling …
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Adsorption behaviour of molecularly imprinted-beta-cyclodextrin polymers prepared by reversible addition-fragmentation chain transfer (RAFT) polymerization for selective recognition of benzylparaben
… on β-cyclodextrin (β-CD) and the essential of reversible addition�fragmentation chain transfer (RAFT) polymerization process were studied to generate potential MIPs. The study focuses on the characterization and adsorption behaviour of MIPs for selective recognition of benzylparaben (BzP) …
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Copolymerizing Acrylonitrile and Methyl Acrylate by RAFT for Melt Processing Applications: A Synthetic Investigation of the Effects of Chain Transfer Agent, Initiator, Temperature, and Solvent
… successfully prepared and characterized using reversible addition-fragmentation chain transfer (RAFT) copolymerization. A typical copolymer was charged with 15 wt. % MA content. This thesis describes a systematic variation of the RAFT copolymerization variables to optimize this system. In …
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Synthesis and study of the micellization behavior of a dual temperature- and pH-responsive PAA-b-PNIPAM block copolymer
… and hydrophilic blocks were synthesized by reversible addition fragmentation chain transfer polymerization. The preliminary results showed high conversion values for all products. Proton nuclear magnetic resonance and ultraviolet–visible spectroscopies were used to study the selfassembly of …
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Synthesis and Characterization of Cation-Containing and Hydrogen Bonding Supramolecular Polymers
… as nitroxide mediated polymerization (NMP) and reversible addition-fragmentation chain transfer polymerization (RAFT). Non-covalent interactions were expected to increase the effective molecular weight of the polymeric precursors through intermolecular associations and to induce microphase …
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Development of Novel Compressible Magnetorheological Fluid (CMRF)
… by force-displacement measurements. The addition of composite polyurethane-microspheres increases the strength and compressibility of the fluid. It also decreases the concentration of iron particles needed in order to achieve the same yield stress as commercially available MR fluid. …
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AB DIBLOCK COPOLYMER NANOPARTICLES VIA RAFT-MEDIATED POLYMERIZATION AS A PSEUDOSTATIONARY PHASE FOR ELECTROKINETIC CHROMATOGRAPHY
… in polymeric synthesis, utilizing the Reversible addition−fragmentation chain-transfer polymerization (RAFT) process, have overcome the aforementioned problems. This study furthers the research of latex nanoparticles as PSPs. 2-Acrylamido-2-methylpropane sulfonic acid (AMPS) was chosen …
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AB DIBLOCK COPOLYMER NANOPARTICLES VIA RAFT-MEDIATED POLYMERIZATION AS A PSEUDOSTATIONARY PHASE FOR ELECTROKINETIC CHROMATOGRAPHY
… in polymeric synthesis, utilizing the Reversible addition−fragmentation chain-transfer polymerization (RAFT) process, have overcome the aforementioned problems. This study furthers the research of latex nanoparticles as PSPs. 2-Acrylamido-2-methylpropane sulfonic acid (AMPS) was chosen …
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Raft Polymerization Of Ph-Responsive, Diblock Copolymers For Nucleic Acid Delivery Vehicles
… polymerization (CRP) and more specifically reversible addition-fragmentation chain transfer (RAFT) polymerization, it is now possible to develop well-defined polymers with predicted molecular weights and architectures. The work presented here focuses on the RAFT polymerization of a family of …
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Examining Structure-Morphology-Property Relationships of Novel Styrenic-Based Macromolecules for Emerging Applications
… rate constants for the copolymerizations with addition of VBIm as comonomer. Reversible addition fragmentation transfer (RAFT) successfully synthesized well-defined A-BC-A triblock copolymers containing a synergy of pendant ether and imidazolium sites. We demonstrated that electromechanical …
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Synthesis and Solution Properties of Semi-rigid Polyelectrolytes and Polyampholytes
… design parameter for microbicidal applications. Reversible addition fragmentation chain transfer (RAFT) polymerization techniques were used to copolymerize 4-diethylaminostilbene with maleic anhydride. These new semi-rigid copolymers were incorporated into double hydrophilic block copolymers …
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Einstufen-Synthese und Charakterisierung amphiphiler Sternpolymere als multifunktionale assoziative Verdicker
… Polymerisation unter Kettenübertragung durch reversible Addition und anschließende Fragmentierung (reversible addition-fragmentation chain transfer, RAFT) genutzt. Die Synthese der Sternpolymere erfolgte von einem multifunktionalen Kern, der die R-Gruppe der RAFT-Kettenüberträger (chain …
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Synthese und Charakterisierung von sensitiven vernetzungsfähigen Blockcopolymeren mittels RAFT
… und Acrylamiden untersucht. Als Methode kam die Reversible-Addition-Fragmentation-chain-Transfer (RAFT) Polymerisation zum Einsatz. Die RAFT wurde gewählt, weil diese im Gegensatz zur ATRP metallionenfrei verläuft und die NMRP nicht für Acrylate geeignet ist. Bei den RAFT-Polymerisationen der …
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Biocompatible polymeric nanoparticles for drug/DNA delivery using biologically friendly polymerisation processes
… several different polymeric nanostructures using reversible addition-fragmentation chain transfer (RAFT) polymerisation in both aqueous and ethanolic solutions.<br/><br/>A preface entailing an abstract, contents, common abbreviations and details of where this work has been presented is …
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