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Showing 1 to 1 of 1 for “"remote functionalization"”.
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I. Synthesis of Ascarosides for Chemical Biology Studies in Caenorhabditis elegans, II. A Photochemical Approach to Delavayine, and III. Remote Hydroxylation by Radical Translocation and Polar Crossover
… 4 details the development of a strategy for remote C-H functionalization using redox catalysis. The Tzo directing group was used to effect 1,6- and 1,7-hydrogen atom transfers from unactivated aliphatics. The resulting radicals were then oxidized by redox (or photoredox) catalysis to form a …