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Showing 1 to 1 of 1 for “"reductive-radical polar crossover"”.
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Reductive Alkylation Reactions Using Tetramethyldisiloxane and Potassium Tert-Butoxide Via Reductive-Radical Polar Crossover
… chapter 2, mechanistic studies suggest the dual radical and polar characteristic of the benzyl nucleophile reactive intermediate, proving the system undergoes the process of reductive-radical polar crossover (RRPC) Ultimately, the TMDSO and KOtBu reagent pair is thought to be synthetically useful …