Global ETD Search
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Showing 1 to 20 of 39 for “"reductive dechlorination"”.
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The Effect of Cyclodextrin on Reductive Dechlorination
… how the addition of cyclodextrin (CD) affects reductive dechlorination of chlorinated ethenes. After chlorinated solvent degradation rates were established in anaerobic and aerobic microcosms, 100 mg/L of CD solution was added for a period of 21 days. CD was then removed after 26 days to …
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Rapid reductive dechlorination of environmentally hazardous aromatic compounds and pesticides
… palladized iron (Pd/Fe), to effect the complete dechlorination of these compounds, at ambient temperature and pressure, in a matter of minutes. The dechlorination reaction occurs on the surface of the palladized iron, with removal of all the chlorine atoms from the chlorinated compound and yields …
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Evaluation of Enhanced Bioremediation for Reductive Dechlorination of Tetrachloroethene (PCE): Microcosm Study
… dehalorespirators were capable of partial dechlorination of tetrachloroethene (PCE) to cis-dichloroethene (cis-DCE). This study attempts to achieve complete reductive dechlorination with amendments to static microcosms to test the hypotheses that nutrient-limited or microorganism-limited …
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Isolation and Ecology of Bacterial Populations Involved in Reductive Dechlorination of Chlorinated Solvents
… species are intimately involved in complete reductive detoxification of chlorinated ethenes and are widely distributed in anoxic sediments and aquifers, including non-contaminated (pristine) environments. Careful examination of enrichment culture dechlorination kinetics, 16S rRNA gene based …
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Compatibility and effectiveness of polymer-enhanced chemical oxidation and reductive dechlorination groundwater remediation strategies
Includes bibliographical references (pages 167-176).
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Spatial Relationship between the Trichloroethylene Degrading Bacteria Dehalococcoides Sp., Sulfate Reducers and Archaea during Reductive Dechlorination
Trichloroethylene (TCE) released to the environment is of great concern due to its toxicity and carcinogencity. The microorganisms involved in bioremediation of TCE such as methanogens (organisms within the domain Archaea), sulfate reducing bacteria (SRB) and Dehalococcoides sp. (DHC) are of …
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Sustainability of reductive dechlorination at chlorinated solvent contaminated sites: Methods to evaluate biodegradable natural organic carbon
Reductive dechlorination is a significant natural attenuation process in chloroethene-contaminated aquifers where organic carbon combined with reducing redox conditions support active dechlorinating microorganisms. At sites where natural organic carbon (NOC) associated with the aquifer matrix …
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Investigation on the Mechanism of Formation and Consumption of Vinylcobalamins Involved in Vitamin B(12)-Catalyzed Reductive Dechlorination of Perchloroethylene
… to further investigate the vitamin B12-catalyzed dechlorination of PCE. Chlorovinylcobalamin 16, previously detected in the PCE dechlorination reaction, was synthesized by treating cob(I)alamin with chloroacetylene. The structure of 16 was confirmed by X-ray crystallography, and is the first …
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Sustainability of Reductive Dechlorination at Chlorinated Solvent Contaminated Sites: Metrics for Assessing Potentially Bioavailable Natural Organic Carbon in Aquifer Sediments
… as a remediation strategy, microbially-mediated reductive dechlorination is typically the dominant pathway for natural attenuation. The efficacy of reductive dechlorination at sites with no anthropogenic carbon sources is often influenced by the availability of readily-biodegradable natural …
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Bioindicators of Reductive Dechlorination in a Dehalococcoides ethenogenes-Containing Mixed Culture: Transcriptional Trends With Respect to Substrate Type, Substrate Concentration, and Culture Operation
… (DET)-containing mixed culture (D2) capable of reductively dechlorinating tetrachloroethene (PCE) successively to trichloroethene (TCE), cis-1,2-dichloroethene (cDCE), vinyl chloride (VC), and non-toxic ethene using H2 as electron donor. Gene transcripts associated with general cell activity, …
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Assessment of Intrinsic Bioremediation at a PCE Contaminated Site
… redox indicators were evaluated to assess the reductive dechlorination potential of Site 12. The results of the groundwater analysis indicated that Site 12 exhibited sulfate-reducing and methanogenic conditions which provide the required environment for reductive dechlorination. However, Site …
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Spatial Relationships Between Potential Bioavailable Organic Carbon and Sediment Grain Size at a Chlorinated Solvent-Contaminated Site
… is possible through the process of microbial reductive dechlorination. Reductive dechlorination can occur in contaminated aquifers where there are sufficient amounts of organic carbon and reducing redox conditions to support dechlorinating microorganisms. Natural organic carbon (NOC) from …
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Degradation Of Halogenated Aliphatic Compounds In Sequential Anaerobic
… by a aerobic methanotrophic environment. Reductive dechlorination of PCE and TCE to cDCE and VC in an anaerobic environment is typically carried out by methanogens, sulfidogens, or homoacetogens but often (e.g. in-situ) leads to an accumulation of daughter compounds (cDCE, VC) which are …
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Investigating the Biostimulating Effects of ESO Addition to a TCE Contaminated Site
… (VC) to non-toxic compounds in a process called reductive dechlorination. Microorganisms that are capable of dechlorination usually require reducing conditions as well as bioavailable hydrogen and carbon sources. Emulsified vegetable oil has emerged as a cost-effective source of degradable …
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A Numerical Model (SEAM3D) to Assess the Biotransformation of Chlorinated Ethenes at a TCE/BTEX Contaminated Site
… to simulate and assess the extent to which reductive dechlorination and direct anaerobic oxidation were responsible for the biotransformation of the chlorinated ethenes. Reductive dechlorination accounted for the 100%, 98.3%, and 97.5% of the biotransformation of TCE, DCE, and VC …
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