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Showing 1 to 1 of 1 for “"pyridyl ligand substituent effects"”.
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Mechanistic Studies of Bimolecular Electron Transfer Self-Exchange Rates of Ruthenium Ammine Pyridyl Complexes Measured by NMR Line Broadening Techniques
… in D<sub>2</sub>O (where L is a substituted pyridyl ligand) were investigated by dynamic NMR measurements. Significant rate enhancement was observed for the cases of L = 3-phenylpyridine and 4-phenylpridine due to possible π-π stacking between Phpy ligands. These observations matche well with …