Global ETD Search
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Showing 1 to 5 of 5 for “"pyridinophane"”.
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Development of systems for isolation of high-valent nickel complexes and their reactivity
… our group utilizing macrocyclic nitrogen based pyridinophane (N4) and triazacyclononane (tacn) ligands for the isolation and study of high-valent nickel and palladium compounds, chiral variants of these ligands were synthesized in attempts to isolate high-valent organometallic nickel complexes …
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Ligand Manipulation and Reactivity Studies of Organometallic High Valent Palladium Complexes
… ligand (N,N'-di-tert-butyl-2,11-diaza[3.3](2,6)pyridinophane). To continue our study in this field, we manipulated the pyridinophane macrocylic ligand by variation of the steric bulk on the amine groups and introduction of strong donating methoxy group on the para position of the pyridine rings. …
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High Valent Palladium Complexes and Their Role in C-C and C-X Bond Formation Chemistry.
… ligand of N,N&rsquo-di-tBu-2,11-diaza[3,3](2,6)pyridinophane (tBuN4), which resembled the early step of methane oligomerization. To further study this process, we modified the tBuN4 by replacing the tBu groups on the amino nitrogen with smaller iPr groups to give iPrN4. Compared to the tBuN4, …
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Development of multifunctional compounds for the modulation and detection of amyloid beta species
… (TACN) and 2,11-diaza[3.3]-(2,6)pyridinophane (N4)-based pyridine metal-chelating compounds were designed and synthesized by incorporating Aβ interacting fragments with metal binding ligands, which allows excellent Cu chelation without losing Aβ binding affinity. Crystal …
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Harnessing the potential of coinage metal redox intermediates
Submission published under a 24 month embargo labeled 'U of I Access', the embargo will last until 2027-08-01