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Showing 1 to 2 of 2 for “"polar transition state"”.
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Hydrogen Abstraction by the Nighttime Atmospheric Detergent NO3·: Fundamental Principles
… solvent effects, and the presence of a polar transition state on NO3· hydrogen abstractions from alcohols, alkanes, and ethers. In this work the acquisition of absolute rate constants from previously unexamined substrates was analyzed alongside a curated list of common organic pollutants …
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Controlling and Exploiting Spiropyran-based Mechanochromism
… probing</p><p>reaction pathways and trapping of transition states and intermediates, has been well–</p><p>studied experimentally and in theory. This work reports on understanding structure property</p><p>relationships for the spiropryan mechanophore and expanding our control of mechanochromism …