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Showing 1 to 4 of 4 for “"photochemical molecular devices"”.

  1. Synthesis and photophysical investigation of supramolecular complexes developed for photoinitiated electron collection

    In this research, photochemical molecular devices were designed to perform photoinitiated electron collection. These devices were synthesized, characterized and their spectroscopic, photochemical and electrochemical properties investigated. The general formula for these systems is …

    vt Repository record for Synthesis and photophysical investigation of supramolecular complexes developed for photoinitiated electron collection (opens in a new tab)

  2. Labile Ligand Variation in Polyazine-Bridged Ruthenium/Rhodium Supramolecular Complexes Providing New Insight into Solar Hydrogen Production from Water

    Mixed-metal supramolecular complexes containing one or two RuII light absorbing subunits coupled through polyazine bridging ligands to a RhIII reactive metal center were prepared for use as photocatalysts for the production of solar H2 fuel from H2O. The electrochemical, photophysical, and …

    vt Repository record for Labile Ligand Variation in Polyazine-Bridged Ruthenium/Rhodium Supramolecular Complexes Providing New Insight into Solar Hydrogen Production from Water (opens in a new tab)

  3. Design and Synthesis of Mixed-Metal Supramolecular Complexes Incorporating Specialized Light Absorbing Units to Investigate Processes Relevant to Catalyst Function

    … was to develop a series of mixed-metal supramolecular complexes with specialized light absorbing units to probe perturbation of excited-state properties by ligand deuteration and long-term complex stability via racemization of initially enantiopure light absorbing subunits. Varying bidentate …

    vt Repository record for Design and Synthesis of Mixed-Metal Supramolecular Complexes Incorporating Specialized Light Absorbing Units to Investigate Processes Relevant to Catalyst Function (opens in a new tab)

  4. Polyazine-Bridged Ru(II),Pt(II) Trimetallic and Tetrametallic Supramolecular Complexes Exhibiting Unusual Excited State Dynamics Important in Catalysis and PDT Drug Development

    … Ru(II),Pt(II) trimetallic and tetrametallic supramolecular complexes and study the impact of component variation on the redox, spectroscopic, and excited state properties that influence photoinduced charged separation and multielectron reduction. These complexes are active photocatalysts for H2O …

    vt Repository record for Polyazine-Bridged Ru(II),Pt(II) Trimetallic and Tetrametallic Supramolecular Complexes Exhibiting Unusual Excited State Dynamics Important in Catalysis and PDT Drug Development (opens in a new tab)