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Showing 1 to 1 of 1 for “"phosphinoboration"”.
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Selective Borylations of Carbon-Carbon pi-Bonds
… unique scaffolds, we developed a selective cis phosphinoboration of 1,3-diynes. In this reaction, a catalytic amount of tributyl phosphine and a diphenyl(4,4,5,5-tetramethyl-1-3-2-dioxaborolan-2-yl)phosphane is used to generate the corresponding cis 1,2-phosphinoboronate in yields ranging from …