Global ETD Search
Search theses and dissertations gathered from participating repositories worldwide. Every result links back to the library that holds it. No account is needed.
Results
Showing 1 to 5 of 5 for “"peroxyoxalate"”.
-
Peroxyoxalate chemiluminescence and capillary electrophoresis : new methods for bioanalytical chemistry
<p>The general research objectives lie in the development of new approaches to improve chemical analysis in the area of bioanalytical chemistry. More specifically this thesis is focused on the development and application of new methodologies and instrumentation involving two potentially powerful …
-
Studies of peroxyoxalate chemiluminescence: Use of electrogeneration and use of a novel reaction medium, supercritical carbon dioxide
Peroxyoxalate chemiluminescence is a commonly used detection method for liquid chromatography. The low detection limits and wide dynamic range that this reaction offers for the analysis of easily oxidizable fluorophores account for the popularity of this detection method.
-
Study of Immobilizing Cadmium Selenide Quantum Dots in Selected Polymers for Application in Peroxyoxalate Chemiluminescence Flow Injection Analysis
<p>Two batches of CdSe QDs with different sizes were synthesized for immobilizing in polyisoprene (PI), polymethylmethacrylate (PMMA), and low-density polyethylene (LDPE). The combinations of QDs and polymer substrates were evaluated for their analytical fit-for-use in applicable immunoassays. …
-
A study of the thermal decomposition of allyl t-butyl peroxide and 3-hydroperoxy-1-propene (allyl hydroperoxide) in toluene /|nby Krishnankutty Nair V. G. -- 260 St. Catharines [Ont. : s. n.],
… mechanism. On the other hand, di-t-butYl peroxyoxalate induced decomposition of this peroxide at 600 proceeded by an abstraction mechanism. Induced decomposition of peroxides and hydroperoxides containing the allyl system is proposed to occur mainly through an addition mechanism at these …
-
CLINICAL APPLICATIONS OF CHEMILUMINESCENCE DETECTION
… of fluorophor labelled immunochemicals using the peroxyoxalate reaction. The effects of fluorophors, esters, and solvents, etc. on the chemiluminescence measurement were evaluated. The conditions for achieving the best precision (1-3% R.S.D.) with a high water component in the measurement were …