Global ETD Search
Search theses and dissertations gathered from participating repositories worldwide. Every result links back to the library that holds it. No account is needed.
Results
Showing 1 to 2 of 2 for “"oxomanganese"”.
-
Kinetic and Spectroscopic Investigation of Structural Influences on Hydrogen-atom Transfer Reactivity of N5-Ligated Oxomanganese(IV) Complexes
… manganese enzymes in nature, several synthetic oxomanganese(IV) species are also capable of activating C-H bonds. However, whereas oxoiron(IV) species have been extensively characterized, the factors that influence HAT reactivity of oxomanganese(IV) species is poorly understood. In an effort to …
-
Mechanistic Investigations of Hydrogen and Oxygen Atom Transfer Reactions by Manganese-Oxygen Species
Metalloenzymes, such as cytochrome P450 and manganese lipoxygenase (Mn-LOX), act as oxidants to perform essentially challenging reactions by activating dioxygen. These reactions commonly feature high-valent metal-oxygen species as key intermediates responsible for the transfer of a hydrogen or …