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Rapid Synthesis, Characterization, and Catalytic Function of Rhodium(III) and Iridium(III) Chloro-bridged Dimers

Brown, LorenVirginia Tech2019

… analysis, and examined as catalysts for oxidative lactonization of 1,4- and 1,5-diols. Oxidative lactonization of 1,4-butanediol to afford γ-butyrolactone proceeded selectively and efficiently using [(η5-Me4C5R)IrCl]2(μ2-Cl)2 as the catalyst. Several R substituents were tested to assess …

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