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Showing 1 to 20 of 393 for “"ortho"”.
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Directed Ortho-Metalation of Dimethylarylamines
… aromatic substitution (EAS) or directed ortho-metalation (DoM). Directed ortho-metalation (DoM) is an alternative aromatic substitution process initiated by organolithium reagents which provides regiospecific substitution exclusively at the ortho- position (equation). The focus of this …
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Hindered Ortho-Vinyl Diaryl Ketones
Made available in DSpace on 2014-12-05T19:37:30Z (GMT). No. of bitstreams: 1 6003963.pdf: 4746035 bytes, checksum: 00d9c931b32ed779c89550d2513bd144 (MD5) Previous issue date: 1960
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Regiospecific Synthesis of Ortho Substituted Phenols
… group (–OH), which is a strongly activating ortho/para directing group in aromatic electrophilic substitution (AES). AES gives a mixture of <em>ortho</em>-and <em>para</em> isomers, which must be separated.</p> <p>The strong directing ability of phenol can also result in multiple …
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Ortho-Planar Mechanisms for Microelectromechanical Systems
A method for representing the design space of ortho-planar mechanisms has been developed. The method is based on the Theorem of Equality of Orientation Set Measures (TEOSM) which allows mechanisms to be represented by points in an abstract space. The method is first developed for single loop planar …
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The Ortho Lithiation of Tertiary Benzamides
… B(OMe)(,3) followed by H(,2)O(,2) to give the ortho substituted products in yields of 52-84%. Similarly, N-N-diisopropylbenzamide was treated with s- or n-BuLi-TMEDA followed by D(,2)O, MeOD, allyl bromide or CO(,2) to give ortho substituted products in yields of 21-87%. A mechanistic study …
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Compliant ortho-planar spring behavior under complex loads
… on the feasibility of applying compliant-ortho-planar springs (COPS) to rotational applications. The primary motivation of this research is the application of COPS to a continuously variable transmission (CVT). The design space limitations, loading conditions, stresses, stress …
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Synthesis and Properties of Ortho-Bridged Triarylmethyl Compounds
The stable carbocation salts 2-tert-butylsesquixanthydryl triflate (2-tert-butyl-4,8,12-trioxadibenzo{cd,mn}pyrenyl trifluoromethanesulfonate) (Ia) and 2,6,10-tri-tert-butylsesquixanthydryl triflate (Ib) are found to be highly delocalized by ('13)C NMR as is expected based on the HMO calculation.
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Synthesis and reactivity of ortho-carborane functionalized boron species.
… the use of highly electron withdrawing and bulky ortho-carborane substituents as Lewis acids for Frustrated Lewis Pair (FLP) chemistry. FLP chemistry is a three-component reaction that involves the use of a Lewis acid (LA), Lewis base (LB) and a substrate. This chemistry has been applied in bond …
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Magnetic Resonance Studies of Ortho-Substituted Derivatives of Triphenylmethane
Made available in DSpace on 2014-12-09T17:35:29Z (GMT). No. of bitstreams: 1 6607806.pdf: 4600909 bytes, checksum: f35f81cad41574e589debc1d88965bc4 (MD5) Previous issue date: 1966
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The ortho-para hydrogen equilibrium in the Uranus atmosphere
Thesis (M.S.)--Massachusetts Institute of Technology, Dept. of Earth and Planetary Science, 1979.
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Directed ortho Metalation in Hydrocarbon Solvents: Opposing Pi-Resonance Effects
… reagents and do not typically support ortho-metalation reactions without the aid of a promoter. An exception would be an arene substrate having the capability to bidentate complex to the reactive alkyllithium dimer, which enables ortho-metalation to occur in high yields. A second, more …
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The reaction of ortho-positronium with nitroaromatics via complex formation
… was made to ascertain the mechanism by which ortho-positronium reacts with nitroaromatics in solution. These reactions are two to three orders of magnitude faster than expected by simple pickoff. Conjugation of the nitro group with the aromatic ring was found to be a necessary condition for …
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Directed Ortho-Metalation of the Three Methyl Anisoles in Various Media
Directed ortho-metalation (DoM) is a very useful alternative to electrophillic aromatic substitution (EAS) for the synthesis of substituted aromatic compounds. DoM is highly regiospecific providing metalation chiefly in the ortho-position. However, lateral (a-) metalation of an alkyl side-chain and …
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Biomimetic synthesis of natural products via reactions of ortho-quinone methides
… products. This thesis will describe the use ortho-quinone methides and cascade reactions towards the biomimetic synthesis of the penilactones A and B, the peniphenones A-D, virgatolide B and epicolactone. The total synthesis of ent-penilactone A and penilactone B has been achieved via …
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