Global ETD Search
Search theses and dissertations gathered from participating repositories worldwide. Every result links back to the library that holds it. No account is needed.
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Showing 1 to 20 of 32 for “"optical band gap"”.
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Processing-composition-structure effects on the optical band gap of KNbO3-based ceramics
This present work is focused on band-gap engineering of solid-solutions based on KNbO3, which was proposed as a promising photoferroelectric (Grinberg et al., 2013). The strategy to narrow the band-gap of the parent KNbO3 (3.22 eV), relies on replacing Nb5+ by lower valence transition metals (Me3+) …
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An investigation into the effect of process parameters on carbon film physical properties produced by different deposition techniques
… relatively poor transmission in the visible. The optical band gap is about 1eV. The refractive index is around 2.2 and their hydrogen content is low.When the carbon content in the source gas was reduced by mixing hydrogen with the hydrocarbon used, the transparency, the content of bonded hydrogen …
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Development of ternary oxides for use in advanced front contacts in cadmium telluride solar cells by magnetron sputtering
… layer was investigated. Important structural, optical, and electronic properties were altered by varying the sputtering ambient composition (oxygen/argon). Incorporation of oxygen in the films causes the films to lose crystallinity and increases the optical band gap through a shift in …
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Fabrication of Zinc Nitride Thin Films using RF Magnetron Sputtering Deposition for Optoelectronic Applications
Zinc nitride thin films possess a small optical band gap with direct transition, low resistivity, high mobility and carrier concentration. Therefore, it may be suitable as an optoelectronic material for infrared sensors, smart windows and energy conversion devices. The objective of this work is to …
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A Universal Heterostructure for Photonic Integrated Circuit Applications
… photonic circuits are investigated using an optical 2 x 2 crossbar switch as a case study. The optical characteristics of slab waveguides are investigated as candidate "universal" structures. Different core profiles, core sizes, and cladding arrangements are considered. A reverse-biased laser …
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Synthesis and characterization of transparent conducting oxides for Stark e ect applications in single molecule spectroscopy
… this mechanism requires a Stark cell. The high optical quality required by the SMS procedure demands a very speci c thickness microscope slide at the objective to sample interface. Since no commercial TCOs of this standard were available, we had to synthesize our own and spincoat our SMS setup's …
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Nanostructured nitrogen and carbon codoped TiO2 thin films: synthesis, structural characterization and optoelectronic properties
… The challenge with TiO2 is that the wide band gap (3.00-3.20 eV) absorbs only ultra-violet (UV) photons and only a small percentage of the solar spectrum is in the UV range. There are various ways to overcome the challenge of sensitizing the material to visible light absorption and this …
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Electrical, electronic and optical properties of MoS2 & WS2
… thickness. Their electrical, electronic and optical properties are of great importance for a variety of applications in optoelectronics as light emitters, detectors, and photovoltaic devices. This work focuses on MoS_2 and WS_2, which are two important members of the TMDC class of materials. …
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Origins and implications of intrinsic stress in hydrogenated amorphous silicon thin films
… conditions and the resulting structural, optical, and bulk properties of the material. In this work we investigate these correlations for a-Si:H films created using plasma enhanced chemical vapor deposition (PECVD), focusing on the creation of intrinsic stresses within the films. Through …
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Characterisation of solution processed zinc oxide quasi-superlattice materials for thin film applications
… measurements, the structural, morphological, optical, electronic and crystallographic properties were investigated. The impact of the number of layer depositions on defect composition, surface roughness, emission spectrum and optical band gap were assessed. The angle-resolved reflectance of …
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Deposition, Characterization, and Fabrication of a Zinc Oxide Piezoelectric Thin Film Microspeaker Using DC Reactive Sputtering
… approach was taken and the structural, optical, electrical, and piezoelectric properties of the ZnO were investigated. Scanning electron microscopy, x-ray diffraction, and atomic force microscopy were utilized to discover the ZnO’s structural properties. Using the XRD and SEM, the …
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Fabrication and optimization of light emitting devices with core-shell quantum dots
… PbS, or another similar compound -- with a wide band-gap "shell" has recently been shown to significantly boost QD-LED performance and yield the most efficient accent QD-LEDs to date. This thesis studies fabrication techniques to make bright, efficient QD-LEDs with these "core-shell" QDs. The …
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Exploring the Optical and Redox Properties of π-Conjugated Boron Difluoride Formazanate Dyes
… to modulate the frontier molecular orbitals and band gaps of these systems. The resulting materials are redox-active and exhibit rich optical properties including high molar absorptivities and low band gaps. Chapter 2 describes a series of acceptor-donor-acceptor compounds consisting of BF2 …
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Single-step, Atmospheric Pressure Chemical Vapor Deposition of Methylammonium Bismuth Iodide Thin Films
… for its non-toxic constituents and favorable optical band gap, thus making it a promising light absorber material. However, manufacturing ready, scale-up processes have not been developed for this compound and this presents a significant roadblock in integrating low-cost, non-toxic Bi-based …
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Hot-wire chemical vapour deposition of nanocrystalline silicon and silicon nitride : growth mechanisms and filament stability
… influenced the structural, mechanical and optical properties of nc-Si:H films mostly when the film thickness is below 250 nm. The film stress, optical band gap, refractive index and crystalline volume fraction approached similar values at longer deposition times irrespective of the …
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IIl-nitride nanowires and heterostructures : growth and optical properties on nanoscale
… light extraction. Material quality and effective band engineering of such III-nitride nanowires are crucial for the design and fabrication of their optoelectronic applications such as LEDs, lasers and photodetectors. In this thesis, we first demonstrate effective control over GaN nanowire size, …
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Deposition of CoxSy, NixSy MnS and CdS thin films from their alkylthiourea precursors using the Aerosol Assisted Chemical Vapour Desposition (AACVD) technique
… (UV) - Visible (Vis) spectra for their optical properties and Energy Dispersive X-ray (EDAX) for the composition of the films. Thin film measurement was performed using the Interferometer method. The X-ray diffraction pattern revealed different phases for the metal chalcogenide film, …
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Carrier transport in undoped and doped films of amorphous arsenic triselenide
… 0.3eV, 0.4eV and 0.6eV above the valence band mobility edge is presented. A new analysis is developed from the concept of a thermally activated capture process. This analysis yields a value for the capture coefficient_y of traps 0.6eV above the mobility edge of 1.1 + 0.5 x 10<sup>-7</sup> …
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SYNTHESIS AND CHARACTERIZATION OF ZINC OXIDE BASED NANOSTRUCTURES AND COMPOSITES FOR ENERGY RELATED APPLICATIONS
… of ~45 nm and lengths of 1–1.3 µm, with an optical band gap of ~3.61 eV. The NWs growth was successfully achieved on various substrates (e.g silicon dioxide, plastic sheets, copper grid, and carbon nanotube buckypaper). The as-prepared ZnO NWs were found to be photoactive under ultra violet …
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Electronic transport properties of thin films of amorphous silicon
… transient and steady state photoconductivity and optical absorption experiments were carried out on thin films of amorphous Silicon. These measurements reveal wide variations in the electronic transport properties of specimens of amorphous Silicon prepared under seemingly identical deposition …
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