Global ETD Search
Search theses and dissertations gathered from participating repositories worldwide. Every result links back to the library that holds it. No account is needed.
Results
Showing 1 to 6 of 6 for “"olefin oxidation"”.
-
Oxygen Atom Transfer Reactions Catalyzed by Molybdenum and Tungsten Oxo Transferase Mimics
The ability to mimic enzymatic oxidation reactions with synthetic catalysts is essential for advancing selective and sustainable chemical transformations. Nature employs molybdenum and tungsten enzymes to mediate oxygen atom transfer (OAT) reactions, which are critical in biological redox …
-
Mechanistic Investigations of Hydrogen and Oxygen Atom Transfer Reactions by Manganese-Oxygen Species
… acids into hydroperoxides via CPET process. The oxidation of C‒H bonds by high-valent iron(IV)-oxo intermediates is quite common in biological enzymes, however, it is rare for Mn(III)-hydroxo species to perform CPET reactions with C‒H bonds. Understanding how these enzymes achieve their …
-
Thermochemistry reaction paths and oxidation kinetics on ketonyl and aldehydic nitrogen oxides, propene and isooctane: a theoretical study
… should lead to better kinetic models for olefin oxidation chemistry the atmospheric.
-
Mechanistic Studies of Rhodium Oxidation Catalysts
… a number of catalytic processes for the O(,2) oxidation of terminal olefins have been proposed to proceed through non-free radical, non-Wacker mechanisms involving the coordination of O(,2) and olefin to a rhodium(I) catalyst. One particularly promising system is the Rh/Cu co-catalyzed O(,2) …
-
Oxidation of Transition Metal Complexes with 3,7-Diazabicyclo[3.3.1]nonane-Derived Ligands
… known [V(IV)=O(N2py3o)]2+ complex (Chapter 6). Oxidation of the latter complex was shown to produce V(V)-oxo-peroxo species in high yields in methanol. To solve the inconsistency of the O-O distance and O-O stretching frequency for the side-on bound peroxo unit in the so formed …