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Showing 1 to 1 of 1 for “"nucleophile Carbene"”.
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Carbene catalyzed asymmetric nucleophilic acylations with novel triazolium salts
… (S)-glutamic acid. With access to the new precarbene catalysts we started to verify their ability to promote the benzoin condensation and intramolecular Stetter reaction. The optimal conditions were identified and allowed for an expansion of the reaction scope with 8-95% yield and enantiomeric …