Global ETD Search
Search theses and dissertations gathered from participating repositories worldwide. Every result links back to the library that holds it. No account is needed.
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Showing 1 to 6 of 6 for “"non-innocent ligands"”.
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Synthesis and Characterization of I. Organometallic Amidophenolate Complexes II. Cyanometallate Frameworks
… the reactivity of organometallic complexes with non-innocent ligands (NIL) was examined. Treatment of PtCl2(diene) with the deprotonated catecholate or amidophenolate ligands afforded the corresponding Pt(NIL)(diene) complexes. The complexes Pt(tBAFPh)(COD), Pt(tBAFPh)(nbd), and Pt(O2C …
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Harnessing Aluminum Radicals via Heterobimetallic Complexes for Small-molecule Activation
… of multiple design strategies, including redox non-innocent ligands and strained coordination geometries, to impart biphilic character to aluminum radicals and precisely tune their reactivity, alongside heterobimetallic frameworks that enable the generation of “masked” Al(II) species capable of …
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Metal-ligand cooperativity in first row transition metals: hydrosilylation catalysis and mechanistic insights
… and ligand, or electronic transformations of the ligands during catalytic reactions. Hydrosilylation of alkenes is one of the most important reactions in the silicone industry, which is currently dominated by catalysts based on PGMs. 1st row transition metal catalysts for this process typically …
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Phenazine: A Building Block for Multinuclear and Heterometallic Complexes, Where the Ligand Acts as an Electron Acceptor and Radical Abstractor
… literature regarding the certain classes of non-innocent ligands containing the six-membered carbon- nitrogen heterocycles and regarding the ligands potentially important for the photochemical applications. We also reviewed all available to the data information about the complexes supported …
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Development Of Ruthenium/terpyridine Complexes For Water Oxidation
… water oxidation catalysts with halogens as axial ligands. In addition, 1H-NMR and ESI mass analysis of complex 1 isolated after catalysis indicated catalyst core remained intact during catalysis. However, the -PhSCH3 substituent on terpyridine was oxidized to -PhSO2CH3 in the presence of strong …
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The Synthesis, Reactivity and Electrochemical Study of Metallocene Substituted α-Diimine Ligands
… metal complexes containing redox-active ligands or ligands with redox-active substituents have been areas of ongoing interest in chemical research. To date, only a handful of examples involving redox-active ligands containing main group centres have been reported. This thesis presents …