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Mixed-valence bimetallic dithiolates of iron, cobalt, and nickel and their relevance to the hydrogenases

Chambers, Geoffrey M.University of Illinois at Urbana-Champaign2016

… dithiolates. The reaction between nickelocene and monothiols has long been known to yield dimers of the form [CpNi(SR)]2 with loss of CpH. The reaction of nickelocene with dithiols is investigated in chapter 4 and is found to be quite complex: dinickel, trinickel, and pentanickel …

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