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Showing 1 to 3 of 3 for “"m-chloroperbenzoic acid"”.
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Studies in regiospecific oxidation reactions of 1-methyl-pentacyclo[5.4.0.02,6.03,10.05,9]undecane-8,11-dione.
… undecane-8,11-dione, performed by using m-chloroperbenzoic acid in 1:1 molar ratio, resulted in the formation of monolactone. The corresponding dilactone, was synthesized by reacting 1-methyl-PCU-8,11-dione with m-chloroperbenzoic acid in 1:2 molar ratio. …
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Baeyer-Villiger Oxidation of 1,7- & 1,9-dibromopentacyclo[5.4.0.02,6.03,10.05,9]undecane-8,11-dione
… was performed by using an excess amount of m-chloroperbenzoic acid (3 equivalents) and resulted in the formation of the corresponding monolactone. The reaction would not proceed to the dilactone stage. The structure of the reaction product was established unequivocally via single crystal X-ray …
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The Synthesis of (+/-)-Presilphiperfol-7(8)-Ene and Tertiary Tricyclo(5.3.1.0(4,11))undecanols Related to Presilphiperfolan-8-Ol
… of the double bond with an aqueous buffered m-chloroperbenzoic acid furnished a 2.5:1 mixture of the 7beta,8beta- and 7beta,8beta-epoxides. m-Chlorobenzoic acid catalyzed a facile rearrangement of the 7beta,8beta-epoxide to 15- nor-cameroon-7-one was investigated. Reaction of nor-PSP-7(8)-ene …