Global ETD Search
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Showing 1 to 2 of 2 for “"ligand noninnocence"”.
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Ultrafast extreme ultraviolet spectroscopy of transition metal dithiolate coordination complexes
… is primarily known for its ligand-noninnocence and participation in the catalytic production of hydrogen. After excitation of [Co(bdt)2]- with visible light, its relaxation dynamics are tracked with a combination of optical and transient M-edge XANES spectroscopic techniques …
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Molecular electrocatalysis of hydrogen evolution: catalytic design studied by density functional theory
… and nickel complexes, the anodic shift due to ligand protonation at proton bridges was found to be greater than the electron-withdrawing effect of replacing the proton with BF2 in both acetonitrile and water. The reverse trend was found for iron, which required much greater overpotential to …