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Showing 1 to 5 of 5 for “"lanthanide coordination"”.
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Design, Synthesis, And Luminescence Properties Of Bridged Dimetallic Lanthanide Coordination Compounds
… nearly isostructural and contained a dimetallic lanthanide core bridged by three oxygen atoms that are covalently bound to the ligand backbone. The homodimetallic Eu3+ complex behaved as a concentration-independent pH sensor that correlates the luminescence-decay rate of the complex to pH. The …
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Ab initio molecular dynamics simulations of lanthanide coordination structures in water and in faujasite
… exchange in faujasite. The structures of the lanthanide aqua ions were resolved with density functional theory calculations and ab initio molecular dynamics (AIMD) simulations within ~0.05 Å of experimental results. Reaction energies were quantified by predicting the first hydrolysis constant …
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The Effect of the Secondary Coordination Sphere on the Stabilities of Cerium(III) and Cerium(IV) Coordination Complexes
The lanthanides, the elements from La–Lu, have intrinsic properties that make them desirable components in many technological applications as well as useful catalysts. However, lanthanides can form unpredictable solid state and solution structures due to their ionic, non-directional, and …
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Synthesis of Inorganic-Organic Hybrid Materials Designed For Radiation Detection, Luminescence, and Gas Storage
… in order to obtain a better understanding of coordination chemistry and structural outcomes, particularly within the area of trivalent lanthanides. Discovering new materials is one route to further advancement of technology; another one is the focus on incremental changes to already existing …
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Polyaminocarboxylic Acids as Potential Candidates for Trivalent Actinide/lanthanide Separations
… trivalent actinides (An(III)s) from trivalent lanthanides (Ln(III)s). Conversely, issues with these reagents have hampered TALSPEAK's implementation as an industrial scale solution. The process requires a high concentration of lactic acid to facilitate phase separations, and the An(III)/Ln(III) …