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Showing 1 to 4 of 4 for “"isocarbostyril"”.
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Total synthesis of lycoricidine via photochemical dearomative dihydroxylation
Lycoricidine a member of the amaryllidaceae isocarbostyril alkaloid family of natural products isolated from bulbs of plants in the amaryllidaceae family, which include the common daffodil. The compound has been demonstrated to possess significant biological activity against a wide range of cancer …
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Dearomative transformations in synthesis: I. Dearomative dihydroxylation with arenophiles II. Total synthesis of lycoricidine and narciclasine III. Towards the total synthesis of collybolide
… all of the carbon atoms present in these isocarbostyril alkaloids. In addition to completing the synthesis of lycoricidine via a nitroso-Diels–Alder reaction and protecting group cleavage, we utilized an aryl C–H hydroxylation strategy for the conversion of a late-stage lycoricidine …
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The development of dearomative functionalizations and their use in the total synthesis of bioactive natural products
Submission published under a 24 month embargo labeled 'Closed Access', the embargo will last until 2024-05-01
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Total synthesis enabled by nickel-catalyzed transformations: Dearomative carboamination and methylenecyclopropane annulation
The use of base metal catalysis is becoming increasingly important, as the sources of transition metals commonly used for the preparation of complex molecules are diminishing. Furthermore, application of these base metal catalysts to the total synthesis of natural products would allow for novel …