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Showing 1 to 3 of 3 for “"iridium-catalyzed borylation"”.
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Iridium-catalyzed borylation of aromatic and aliphatic C-H bonds: methodology and mechanism
… conduct the one-pot, meta cyanation of arenes by iridium-catalyzed C-H borylation and copper-mediated cyanation of the resulting arylboronate esters is described in Chapter 2. This process relies on a previously unknown method to conduct the cyanation of arylboronic esters, and conditions for this …
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A hydrogen bonding ortho-directing effect for the iridium catalyzed borylation of NH(t-BOC) aromatics
The C-H borylation of aromatic substrates has evolved from a stoichiometric curiosity to a valuable methodology for the synthetic chemist. Understandings of regioselective activation and high functional group tolerance have been considerably praised. Most aromatic substituents, such as alkyl, …
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New methodologies and approaches to reaction discovery in transition metal catalysis
… synthetic methods have been developed based upon iridium-catalyzed borylation of aromatic and heteroaromatic C-H bonds. A general, one-pot method for alkylation of arenes with the site-selectivity controlled by steric effects as opposed to electronic effects via Ir-catalyzed C-H borylation …