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Showing 1 to 2 of 2 for “"ion-pair separation"”.

  1. Computational Studies of Protonated Cyclic Ethers and Benzylic Organolithium Compounds

    … as reactive intermediates. Gas-phase calculations studying the structure and ring-opening energetics of protonated ethylene oxide, propylene oxide and 2-methyl-1,2-epoxypropane were performed at the B3LYP and MP2 levels (both with the 6-311++G** basis set). Structural analyses were performed …

    vt Repository record for Computational Studies of Protonated Cyclic Ethers and Benzylic Organolithium Compounds (opens in a new tab)

  2. Study of Synthesis, Reactions and Enantiomerization of C<sub>α</sub>-Chiral Grignard Reagents

    … with their synthesis, and their low configurational stability. We have studied these problems in three different modules of this project. Reactions of 1-magnesio-2,2-diphenyl-cyclopropylcarbonitrile with carbon electrophiles are first attempted in order to expand the utility of this …

    vt Repository record for Study of Synthesis, Reactions and Enantiomerization of C<sub>α</sub>-Chiral Grignard Reagents (opens in a new tab)