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Showing 1 to 2 of 2 for “"hydroxyethylphosphonate dioxygenase"”.
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Investigation of phosphonate biosynthesis: I. Structure of dehydrophos II. Mechanism of hydroxyethylphosphonate dioxygenase
… and through investigations into the mechanism of hydroxyethylphosphonate dioxygenase. Dehydrophos was discovered as a secondary metabolite of Streptomyces luridus and was shown to have broad spectrum activity against both Gram-negative and Gram-positive bacteria. Chemical synthesis of the …
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Mechanistic investigations of enzymes in phosphonate metabolism
… my contributions toward this enterprise. 2-Hydroxyethylphosphonate dioxygenase (HEPD) is a non-heme iron enzyme that catalyzes the cleavage of the carbon-carbon bond of 2-hydroxyethylphosphonate (2- HEP) during the biosynthesis of the herbicide phosphinothricin. Mechanistic studies were …