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Showing 1 to 5 of 5 for “"hydrosilane"”.
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Development and Mechanistic Investigation of Indium(III)-Catalysed Hydrosilane Reduction of Imines
… have been investigated as catalysts for the hydrosilane reduction of imines. The functionalised BINOL ligands employed include a range of C1-symmetric BINOL ligands, which were synthesised as part of a project on optimising BINOL phosphoric acid ligands described in Chapter 2. Significant …
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Creation of crosslinkable interphases in polymer blends by means of novel coupling agents
… SCA) containing 2-oxazoline, 2-oxazinone, and hydrosilane reactive sites have been prepared. In blends of amino- functional and carboxylic acid terminated polymers the oxazoline and oxazinone units of the SCA react selectively with one of the polymers and, therefore, the SCA should locate at …
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Electrophilic C(sp²)–H Cyanation with Inorganic Cyanate (OCN⁻) by Pᴵᴵᴵ/Pⱽ=O-Catalyzed Phase Transfer Activation
… be easily achieved by the usage of a terminal hydrosilane reductant. These results demonstrate the feasibility of deoxyfunctionalization of insoluble inorganic salts by Pᴵᴵᴵ/Pⱽ=O catalyzed phase transfer activation, as exemplified by C(sp²)–H cyanation with NaOCN as the “CN⁺” source.
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Synthesis of Functionalized Poly(dimethylsiloxane)s and the Preparation of Magnetite Nanoparticle Complexes and Dispersions
… (DIPCS). Platinum-catalyzed hydrosilation of the hydrosilane-terminated PDMS with allyloxyethanol afforded a systematic series of hydroxyalkyl-terminated PDMS. The reactions were successful except for the hydrosilation of the sterically-hindered DIPCS-functionalized PDMS where no reaction was …
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Reductive Alkylation Reactions Using Tetramethyldisiloxane and Potassium Tert-Butoxide Via Reductive-Radical Polar Crossover
Hypervalent silicon compounds have shown increasing applications and synthetic versatility throughout recent years due to their unique reactivity. In this study, the combination of alkoxide base and silicon hydride species – potassium tert-butoxide (KOtBu) and 1,1,3,3-tetramethyldisiloxane (TMDSO) …