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Showing 1 to 5 of 5 for “"hydroperoxyl radical"”.
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A Determination of the Rate Constant and Products for the Reaction of the Chlorine Oxide Radical With the Hydroperoxyl Radical
Made available in DSpace on 2014-12-13T20:10:49Z (GMT). No. of bitstreams: 1 8009083.pdf: 4294480 bytes, checksum: 5ed6dc3f6b77a8d796caf7339d23b0eb (MD5) Previous issue date: 1979
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Kinetic and Mass Transfer of Peroxone Oxidation of Toluene Using Ultra Sonic Spray: Ab Initio Quantum Calculations and Numerical Modeling
… in gas and aqueous phases considering the ozone-hydroperoxyl radical reaction and the dissociation equilibrium of the hydroperoxyl radical. The predictions of the ozone degradation rate at low pH (<6) is improved by up to two orders of magnitude over existing models. For peroxone oxidation of …
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Oxidation Mechanisms of Tetrahydrofolic Acid, Tetrahydrobiopterin and Related Compounds
… rate-determining. Kinetic data suggest a free radical chain reaction in which the chain carrier is the hydroperoxyl radical (HO2.) and that intermediate hydroperoxides are not involved. Quinonoid dihydropterins are obligatory intermediates, their rearrangement leading to the observed products. …
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Laboratory measurements and modeling of trace atmospheric species
… An experiment for the detection of the hydroperoxyl radical employing the edge-tuner in the ICLA Spectrometer is discussed and proposed. The results from the laboratory measurements are followed by the presentation of a near-explicit kinetic box model designed to improve our …
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Investigation of methods for reducing aflatoxin contamination in distillers grains
… and oxidation of the furan ring. The hydrogen radical, hydroxyl radical, hydroperoxyl radical and ozone were proposed as the major reactive agents for AFB1 degradation generated by HVACP treatment. Based on the literature, the degradation produced changes in the furofuran and lactone rings, and …