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Showing 1 to 3 of 3 for “"hybrid orbitals"”.

  1. Calculations of small transition metal molecules relating to catalysis

    … It was found that the transition metal 3d-orbitals do not participate significantly in the bonding of these molecules. Rather, the bonds involve mainly the 4s and 4sp hybrid orbitals. The diatomic hydride molecules were found to have a radical state with a highly reactive singly occupied …

    uiuc Repository record for Calculations of small transition metal molecules relating to catalysis (opens in a new tab)

  2. Palladium and platinum complexes of substituted 4-vinylcyclohexene

    … pi electrons in the unsaturated molecule and the hybrid orbitals of the metal rather than a localized sigma bonds between the metal atom and a particular carbon atom. The metal was complexed to a hydrocarbon which possessed a surplus of electrons. The direct overlap of a sigma orbital of the metal …

    u-pacific Repository record for Palladium and platinum complexes of substituted 4-vinylcyclohexene (opens in a new tab)

  3. Molecular Electronic Structure via Photoelectron Imaging Spectroscopy

    … angular distributions resulting from mixed s - p hybrid states is presented and applied to detachment from pyridinide, C₅H₄N⁻; as a benchmark system. Before further exploring this model, the synthesis of several deuterated heterocyclic compounds is presented in order to determine the …

    arizona-thes Repository record for Molecular Electronic Structure via Photoelectron Imaging Spectroscopy (opens in a new tab)