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Showing 1 to 5 of 5 for “"high valent palladium"”.
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Organometallic chemistry of high-valent palladium and rhodium complexes
Author requested closed access (OA after 2yrs) in Vireo ETD system
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Ligand Manipulation and Reactivity Studies of Organometallic High Valent Palladium Complexes
<p>Catalysis involving high-valent Pd(III) and Pd(IV) complexes has recently shown important applications in the development of new chemical transformations that compliments conventional Pd<super>0/II</super> catalysis.</p><p>However, the Pd(III) or Pd(IV) intermediates cannot be …
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Oxidative reactivity of high-valent palladium complexes supported by 1,4,7-triisopropyl-1,4,7-triazacyclononane
Submission published under a 24 month embargo labeled 'Closed Access', the embargo will last until 2026-08-01
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Palladium-mediated C–H Functionalization of Aliphatic Amines via High Valent Palladium(IV) Intermediates
… to oxidize amine-derived palladacycles to high valent PdIV intermediates capable of undergoing a variety of reductive elimination pathways to afford a diverse range of functionalized products. Hypervalent iodine(III) reagents were initially investigated as oxidants in the development of a …
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High Valent Palladium Complexes and Their Role in C-C and C-X Bond Formation Chemistry.
… transfer steps. This translates into a very high barrier of activation since multi-electron processes are kinetically challenging. On the other hand, multi-nuclear complexes are receiving an appreciable interest due to their potential synergetic effect between the metals. To this purpose, …