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Showing 1 to 3 of 3 for “"hemiketal"”.

  1. Mechanistic investigation of human cytochromes P450 involved in hormone biosynthesis

    … reaction proceeds through a non-conventional hemiketal intermediate. However, it remains unknown if the alternate substrate, 17-hydroxy-progesterone (OH-PROG) is transformed to androstenedione via this novel mechanism, by the traditional compound I (Cpd I) mechanism, or by a combination of the …

    uiuc Repository record for Mechanistic investigation of human cytochromes P450 involved in hormone biosynthesis (opens in a new tab)

  2. The Colloidal Stabilization of Quantum Dots: Towards Manufacturable, Efficient Solution-Processed Solar Cells

    … a new ink strategy, which I term cleavable hemiketal ligands. This novel two-component ligand strategy enables the combination of colloidal stabilization (via this longer two-component ligand) and cleavability (enabling excellent packing in film and, ultimately, excellent electronic …

    toronto-retro Repository record for The Colloidal Stabilization of Quantum Dots: Towards Manufacturable, Efficient Solution-Processed Solar Cells (opens in a new tab)

  3. Some chemistry of orthomanganated ketones

    … by-product from the oxidation of (4), the cyclic hemiketal, (36), was identified by X-ray crystal structure analysis, and one other product, the lactone, (37) was identified spectrally. Determination by ¹H-NMR of the ratio of the 3-deuterio- (1a) to 3-protio- (1) formed in the orthometallation of …

    waikato-masters Repository record for Some chemistry of orthomanganated ketones (opens in a new tab)