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Showing 1 to 2 of 2 for “"heats of dilution"”.

  1. An Improved Model for Calculating Heats of Dilution and Equilibrium Constants for High Temperature Aqueous Electrolyte Solutions

    At high temperatures, the properties of aqueous electrolyte systems differ markedly from those at 25°C. For mixed-electrolyte dilute solutions at high temperatures, the degree of ion-association is sufficiently large that the association equilibrium must be incorporated in any model describing the …

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  2. Properties Model for Aqueous Sodium Chloride Solutions near the Critical Point of Water

    Traditional excess Gibbs energy models in terms of temperature, pressure, and concentration become progressively less effective in describing the thermodynamics of aqueous solutions at temperatures above 300 ¢ªC, and are totally inadequate in the critical region of water. This deficiency is due …

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