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Showing 1 to 5 of 5 for “"haloalkane"”.
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New Strategies in Radical Chemistry and Their Application to the Construction of C(sp3)–C(sp3) Bonds in the Giese Reaction
… derived from an interaction between the haloalkane and silane. The optimal setup was pleasingly compatible with a broad range of alkyl iodide and acceptor scaffolds, incorporating valuable functionalities such as free alcohols, protected amines and biologically active compounds. Further …
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Extending the utility of enzymes for site-specific targeting of fluorescent probes
… In another example, we show that LplA-targeted haloalkanes can efficiently recruit a modified haloalkane dehalogenase. These methods were used to label cells with diverse fluorophores, including quantum dots, and allowed tracking of single membrane proteins to study their lateral diffusion.
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Investigating Controls on Variation in Isotopic Fractionation during Biodegradation of Chlorinated Ethenes and Ethanes
… may affect observed isotope fractionation. Two haloalkane dehalogenases catalyzed aerobic 1,2-dichloroethane (1,2-DCA) dechlorination with very different enzyme affinities and turnover rates. However, carbon isotope enrichment factors were the same for both enzymes, reflecting the intrinsic …
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Synthesis, structure and reactivity of chiral cyclopentadienylruthenium(II) complexes
… -C 5 H 5 )Ru(PPh 3 )(CNt Bu)(Ti 2 -H2)]PF6 (e.g.,haloalkane, aldehydes, ketones, alkene).Complexes containing an asymmetrically disubstituted rc-bonded ligand, TJ -1-ethyl-3-methylcyclopentadiene which induces planar chirality, e.g., [(r| 5 -l-Et-3-Me-C 5 H 3 )Ru(PPh3 )(L)Cl] (L - PPh 3 , CN'Bu, …
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Halocarbon Reactions on the Chromium (III) Oxide (101̲2) Surface
A nearly stoichiometric, (1×1) Cr₂O₃ (101̲2) surface was prepared from a single crystal of α-Cr₂O₃. The five-coordinate cations exposed at the stoichiometric surface dissociatively adsorb molecular oxygen to form a (1×1), terminating chromyl (Cr=O) layer that is stable to >1100 K. TDS and AES were …