Global ETD Search
Search theses and dissertations gathered from participating repositories worldwide. Every result links back to the library that holds it. No account is needed.
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Showing 1 to 5 of 5 for “"halide loss"”.
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Ru,Rh,Ru Supramolecular Photocatalysts within Nafion® Membranes: Ion-exchange, Photoelectrolysis and Electron Transfer Processes
… experiment. This enhancement is attributed to halide loss following the first reduction process. Lastly, electrospun carbon nanofiber mats behave as electron donor materials for [{(bpy)2Ru(dpp)}2RhBr2] 5+/Nafion® membranes.
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Electrospray-friendly ligands for the mass spectral analysis of transition-metal complexes
… metal carbonyl complexes of Mo, Fe and Ru, metal halide complexes of Pd, Pt and Au, and a number of zero-valent complexes of Pt and Pd. All carbonyl complexes with ES-friendly phosphine, arsine and stibine ligands ionised by protonation, yielding strong [M + H]⁺ ions as the only signals in the …
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Probing the Redox and Photophysical Properties of Ru(II)-Pt(II) Supramolecular Complexes as Efficient Photodynamic Therapy Agents
… the Pt(II) a weaker Lewis acid and promoting halide loss. In addition, this system is photoactivated with low energy red light in the therapeutic window. These studies validate the supramolecular design and show that coupling a Ru(II) chromophore for PDT activity and a cis- PtCl₂ binding …
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Design and Modification of Polyazine-Bridged Ru(II),Rh(III) Bimetallic and Trimetallic Supramolecular Complexes Applicable in Solar Energy Harvesting for the Photocatalytic Reduction of Water to Hydrogen
… terminal ligands (TL), non-chromophoric halides (X), or number of Ru(II) light absorbers (LA) tunes the electrochemical, spectroscopic, photophysical, and photochemical properties within the supramolecular architecture. Ru(II),Rh(III),Ru(II) trimetallics of the design …
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New Polyazine-Bridged Ru(II),Rh(III) and Ru(II),Rh(I) Supramolecular Photocatalysts for Water Reduction to Hydrogen Applicable for Solar Energy Conversion and Mechanistic Investigation of the Photocatalytic Cycle
… established that two halides on RhIII are not necessary in the dpp-bridge RuII,RhIII supramolecular photocatalytic-water-reduction system. This new discovery opens a new approach to the design of different RuII,RhIII motifs for photocatalysis. The active species for …