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Showing 1 to 5 of 5 for “"grand potential"”.

  1. Finite-temperature many-body perturbation theory for electrons

    … to the electronic internal energy, chemical potential, grand potential, and entropy of an ideal gas of noninteracting, identical molecules in a wide range of temperature were determined numerically as the λ-derivatives of the respective quantity calculated exactly by a thermal full …

    uiuc Repository record for Finite-temperature many-body perturbation theory for electrons (opens in a new tab)

  2. Surfactant Aggregation in the Bulk Fluid and at the Fluid-Wall Interface

    … concentrations. Solvent and surfactant chemical potentials are determined using both the Widom test particle and the Powles f-g sampling methods. Cluster size distributions are used to demonstrate the thermodynamics of cluster equilibria. The effect of bulk surfactant concentration on the …

    uiuc Repository record for Surfactant Aggregation in the Bulk Fluid and at the Fluid-Wall Interface (opens in a new tab)

  3. A multiscale theory to determine thermodynamic properties of confined fluids

    Empirical potential-based quasi-continuum theory (EQT) provides a route to incorporate atomistic detail into a continuum framework such as the Nernst- Planck equation. EQT is a simple and fast approach to predict inhomogeneous density and potential profiles of confined fluids. EQT potentials can be …

    uiuc Repository record for A multiscale theory to determine thermodynamic properties of confined fluids (opens in a new tab)

  4. A multiscale framework for structure of confined water and electrolytes

    … theories. In this work, we present an empirical potential based quasi-continuum theory (EQT) to accurately predict the molecular-level properties of interfacial water and aqueous electrolytes. In EQT, we employ rigorous statistical mechanics tools to incorporate interatomic interactions, …

    uiuc Repository record for A multiscale framework for structure of confined water and electrolytes (opens in a new tab)