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Showing 1 to 3 of 3 for “"giese reaction"”.
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New Strategies in Radical Chemistry and Their Application to the Construction of C(sp3)–C(sp3) Bonds in the Giese Reaction
… to build saturated hydrocarbon frameworks (the Giese reaction), is investigated. The transformation merges two electrophilic components (an alkyl halide and an acceptor) in the presence of a silane and visible light irradiation. Under these mild and extraordinarily simple conditions, visible …
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Utilising Non-Covalent Interactions in Developing Enantioselective Radical Transformations
… enantioselective strategies for radical reactions, utilising non-covalent interactions to control the asymmetry of these processes. The first research chapter describes the use of chiral phosphoric acids to control the enantioselectivity in the reactions of α-amino radicals. Firstly, a …
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Adiciones 1,4-conjugadas a deshidroalaninas quirales para la síntesis de aminoácidos no naturales
… Chapter 3, a study of the Michael-type addition reaction with N-, Se- and C-nucleophiles has been developed. Thanks to this methodology, derivatives of α,β-diamino acids and bis-α-amino acids can be obtained, among which histidinoalanine, which is related to cellular aging, can be highlighted. On …