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Showing 1 to 3 of 3 for “"gallium(I"”.
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Synthese und Strukturen verschiedener neuer Galliumsilyle und eines Hexagallans mit Hilfe maßgeschneiderter Silanide
… mit niedervalenten Galliumhalogeniden konnten die dreiwertigen Galliumsilanide Ga{Si(SiMe3)2Me}3, [Ga{Si(SiMe3)2Me}3I]- sowie das Hexagallan [Ga{Si(SiMe3)2Me}]6 isoliert werden. Die Stabilisierung dieses hexameren Gallium(I)silanids wurde durch die Verwendung der …
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Reactivity of a Low Valent Gallium Compound
… to expand the reactivity of the β-diketiminate gallium(I) compound, NacNacGa (NacNac=[ArNC(Me)HC(Me)NAr]−, Ar=2,6-iPr2C6H3). The reactivity of NacNacGa towards various unsaturated compounds is studied. In particular, reaction between NacNacGa and phenyl isothiocyanate resulted in the oxidative …
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INTERMOLECULAR COMPLEXES OF GERMANIUM(II
… diisopropylphenyl-substituted N-heterocyclic gallium® (NHGa') ligand or a diisopropyl substituted N-heterocyclic carbene (NHC) ligand were synthesized by the addition of two equivalents of either NHGa' or NHC to tetramesityldigermene (Mes2Ge=GeMes2). The complexes [NHGa-GeMes2] and NHC- GeMes2 …