Global ETD Search
Search theses and dissertations gathered from participating repositories worldwide. Every result links back to the library that holds it. No account is needed.
Results
Showing 1 to 4 of 4 for “"ethyl diazoacetate"”.
-
Investigations into cyclopropanation and ethylene polymerization via salicylaldiminato copper (II) complexes
… reactions. Cyclopropanation of styrene and ethyl diazoacetate (EDA) is a standard test reaction for homogeneous catalysts. Sterically bulky salicylaldimine (SAL) ligands should select for the ethyl trans-2-phenylcyclopropanecarboxylate diastereomer. Steric bulk poorly influences trans:cis …
-
Mechanistic study and protein engineering of a dye-decolorizing peroxidase from Thermomonospora curvata for enhanced and expanded functions
… the cyclopropanation of styrene with ethyl diazoacetate, demonstrating the feasibility of repurposing DyPs for new chemical transformations. The enzyme scaffold not only accommodated the artificial metal center but also influenced diastereo- and enantioselectivity, which was further …
-
Diverse Applications of Flow Technology in Discovery Chemistry
… unexpected carbon-carbon bond forming event of ethyl diazoacetate and acetonitrile. Finally, in a follow-up study, collaboration with Boston University was continued to explore additional reactivity of the bicyclo[3.2.1]octanoid scaffold. Preliminary reaction screens uncovered the synthesis of a …
-
SOLID-SUPPORTED PORPHYRINS FOR CATALYSIS AND SENSING
… sheets. The cyclopropanation of α-methyl styrene by ethyl diazoacetate (EDA) was employed in solvent-less condition as the model reaction to test the catalytic efficiency of CC-based heterogeneous catalysts. Before testing the heterogeneous catalyst, the catalytic activity of the …