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Control of selectivity in palladium-catalysed cross-coupling reactions using a sulfonated phosphine ligand

Pearce-Higgins, RobertUniversity of Cambridge2021

… are routinely used by enzymes to control selectivity of chemical reactions during biosynthesis. This prevalence in nature has inspired chemists to adapt these interactions to control selectivity in small molecule catalysis. This thesis describes efforts towards utilising non-covalent …

cambridge Repository record for Control of selectivity in palladium-catalysed cross-coupling reactions using a sulfonated phosphine ligand (opens in a new tab)

Palladium-katalysierte kinetische Racematspaltung allylischer Carbonate mit S-Nukleophilen und enantioselektive Umlagerung allylischer O-Sulfinate : asymmetrische Synthese von allylischern Sulfiden und Sulfonen

Jagusch, ThomasPublikationsserver der RWTH Aachen University2003

… BPA as ligand proceed with excellent levels of enantio-selectivity in both kinetic resolution and substitution. While the kinetic resolution allows for the synthesis of enantiomerically highly enriched cyclic and acyclic allylic alcohols up to 99% ee, the substitution provides for an asymmetric …

aachen Repository record for Palladium-katalysierte kinetische Racematspaltung allylischer Carbonate mit S-Nukleophilen und enantioselektive Umlagerung allylischer O-Sulfinate : asymmetrische Synthese von allylischern Sulfiden und Sulfonen (opens in a new tab)

Studies on Chemo- and Site-Selective C-H Amination of Aniline and Phenol Derivatives with Dirhodium Catalysts and Catalytic Asymmetric Synthesis of Inherently Chiral Calixarenes

Chen, GongKyoto University2021

kyoto Repository record for Studies on Chemo- and Site-Selective C-H Amination of Aniline and Phenol Derivatives with Dirhodium Catalysts and Catalytic Asymmetric Synthesis of Inherently Chiral Calixarenes (opens in a new tab)