Global ETD Search
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Showing 1 to 5 of 5 for “"electron paramagnetic spectroscopy"”.
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Polyoxometalates and Block Copolymers: Templated Self-Assembly for Nanomaterials Applications
… and ferromagnetic exchange interactions, while electron paramagnetic spectroscopy provides information into the electronic structures of POMs. The feasibility of templating POMs with block copolymers is demonstrated in a preliminary ionic exchange reaction. Block copolymers were explored as …
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pH MODULATION OF FIBRIL DISSOCIATION AND COPPER BINDING PROPERTIES OF THE PRION PROTEIN
… isothermal titration calorimetry and X-band electron paramagnetic spectroscopy. Our results confirm that copper binding to both the octarepeats and the fifth binding site is pH-dependent. We show that both sites bind copper in the fibrillar form with coordination modes similar to their …
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pH MODULATION OF FIBRIL DISSOCIATION AND COPPER BINDING PROPERTIES OF THE PRION PROTEIN
… isothermal titration calorimetry and X-band electron paramagnetic spectroscopy. Our results confirm that copper binding to both the octarepeats and the fifth binding site is pH-dependent. We show that both sites bind copper in the fibrillar form with coordination modes similar to their …
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Metalloprotein engineering with unnatural amino acids: application in functional heme-copper oxidase and azurin
… of radical under H2O2 reaction condition by electron paramagnetic resonance (EPR) spectroscopy. Simulation of X- and Q-band EPR spectra suggested this radical is a tyrosyl radical, while natural amino acid mutagenesis and unnatural amino acid incorporation proved this radical is at Tyr33, the …
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Molecular detection and charcaterisation of biologically relevant free radicals during surgical ischaemia-reperfusion
… values. Calculated molecular structures, EPR (electron paramagnetic resonance spectroscopy), the vibration spectral and energetic properties and all are reported including some proposed changes to previous EPR assignments. Conformer 2 of L-ascorbic acid is predicted to have lower energy than …