Global ETD Search
Search theses and dissertations gathered from participating repositories worldwide. Every result links back to the library that holds it. No account is needed.
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Showing 1 to 5 of 5 for “"effective molarity"”.
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Endocyclic Nucleophilic Methyl Transfer
… pathway and the results are consistent with an effective molarity of less than 3 x 10('-5) M for the endocyclic process. Similarly, the formation of 2-(trimethylammoniomethyl)phenylmethanesulfonate from methyl 2-(dimethylaminiomethyl)phenylmethanesulfonate in benzene with initial ester …
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Replication of Sequence Information in Recognition-Encoded Synthetic Polymers
… provide a pathway for error correction. The effective molarity for the intramolecular reactions that lead to templating using this system was determined to be 3 mM, meaning that oligomerisation reactions had to be carried out at low concentrations. Difficulty in performing dynamic imine …
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Multivalent Supramolecular Systems
… H-bonded rosette system was revisited and the effective molarity was determined experimentally by 1H NMR titrations to be around 2 M, which is a high chelate cooperativity compared to other supramolecular systems. Moreover, the concept of peripheral crowding in solution was revisited, since …
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Hydrogen Bond Template-Directed Synthesis of Recognition-Encoded Melamine Oligomers
… REMO 6-mer phosphine oxide template. The effective molarity for the intramolecular reaction that led to the templated product was found to be 2 mM, enabling efficient template-directed synthesis to be carried out at μM concentrations. The major competing reaction was templated …
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Modular synthesis-enabled mechanistic characterization of the potent antilipoperoxidant activity of peridinin
… revealed that the potency is linked to a high effective molarity within lipid bilayers. In contrast to the primarily extramembranous localization of the less effective antilipoperoxidant astaxanthin, peridinin is completely embedded within and physically spans the hydrophobic core of lipid …